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A dendritic aromatic 12-carboxyl ligand (H12TDDPB) is assembled with Zn(II) ion. The TDDPB dimer coordinated with 12 Zn(II) ions, regarded as a dodecapus, is stabilized by metal coordination and π–π ...

Targeting open Mo coordination sites, decarbonylation was pursued. Oxidation of 2 with 2 equiv of silver trifluoromethanesulfonate liberated one of the carbonyl ligands, increasing the hapticity of ...