Nitrenium salts have been known for more than 100 years. Despite being isoelectronic and isostructural to the ubiquitous N-heterocyclic carbene ligands and other main-group analogues, their ...

Nickel(0) and boron—together at last in square-planar complexes. The arrangement of small molecules—known as ligands—around transition metal atoms affects how the metal atoms behave.

Density functional theory (DFT) is a cornerstone tool of modern physics, chemistry, and engineering used to explore the ...