LONDON — Belvedere’s new coffee-based vodka will get tipplers buzzed, one way or another. Titled Belvedere Dirty Brew, the spirit retails for $50 and is available to purchase at Selfridges.

How do you make vodka exciting? Belvedere thinks it has the answer with a new expression called 10, a single-estate luxury vodka that was rested for nearly a year before being bottled in a ...